Classification of Heat Evolution Terms in Li-Ion Batteries Regarding the OCV Hysteresis in a Li- and Mn-Rich NCM Cathode Material in Comparison to NCA

نویسندگان

چکیده

We investigate the heat release of Li- and Mn-rich NCM (LMR-NCM) NCA half-cells during cycling at different C-rates quantify individual contributions to overall flow using a combination isothermal micro-calorimetry electrochemical methods. The paper focuses in particular on open-circuit voltage (OCV) hysteresis LMR-NCM material, which results significant reduction energy round-trip efficiency (≈90% for LMR-NCM/Li cells vs ≈99% NCA/Li C/10) therefore an additional source that has be considered thermal management cell. total is found nine times higher than corresponding (at C/10). In case cathode, due OCV responsible up 55% loss. Using applied approach, separated into its share charge discharge furthermore presented as function SOC. Additional sources heat, such reversible entropic parasitic effects, measurement limitations, are discussed terms their contribution balance two cell chemistries.

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ژورنال

عنوان ژورنال: Journal of The Electrochemical Society

سال: 2022

ISSN: ['0013-4651', '1945-7111']

DOI: https://doi.org/10.1149/1945-7111/ac6541